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https://steemit.com/static/search.html?q=when+to+vote

@1min Author gets 99% of the 25% curation reward
@20mins Author gets 33% & voters gets 66% of the 25% reward
@31mins Voters gets 100%

Voters % split is dictated by # voters & their Votepower% & their SP

I suggest 10-25mins or even 30mins
Beating "whales" to vote is the idea, but you don't know if / when they will. (Most whale bots vote @ 10-20mins)

Hope that helps.
Welcome to steem :-)
ps HELP search is a great way to learn the platform, Lots & lots to learn!!
Happy to assist if you need assistance.

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